求Australian Journal of Chemistry 一篇
【题名】:The preparation of some .beta.-sulfonylacrylate thioesters and .beta.-sulfonylvinyl ketones.【作者】:RK Haynes, SC Vonwiller, JP Stokes and LM Merlino
【杂志名全称】:Australian Journal of Chemistry
【年, 卷(期), 起止页码】:Australian Journal of Chemistry 41(6) 881 - 895
【DOI】:Full text doi:10.1071/CH9880881
【全文链接】:[url]http://www.publish.csiro.au/nid/51/paper/CH9880881.htm[/url]
【摘要信息】:β- Sulfonylacrylate phenyl and t-butyl thioesters , and β- sulfonylvinyl ketones have been prepared by oxidation of the corresponding β-aryl- and β-alkyl- thio compounds. In one case the β- sulfonylvinyl ketone was obtained from an epoxy sulfone . The β-aryl- and β-alkyl- thio compounds were obtained by chlorination- dehydrochlorination of saturated precursors. The reactions of 3-( phenylthio ) propionyl chloride with organocadmium and Grignard reagents were used to prepare some of the saturated precursors of the β- sulfonylvinyl ketones.
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